Adding C20 (330pF) is not going to help you. It will pass more high frequencies, bypassing R42. I tried it and ended up removing it because it made the amp way too bright when the gain wasn't cranked up. It adds an interesting flavor the the dirt when the gain is cranked, but didn't work for me with clean tones.
For me, the trick with EQing the 18W amp was balancing the cathode bypass caps on V1 and coupling caps from V1 to V2 with the distortion tone. Caps that are too large in those spots will muddy up the distortion. But having a nice distortion leaves the amp with a bland clean tone. I really like the stock values in the Plexi Mk II design for distortion tone (sans C20). For me, the answer was the NFB loop, with resonance and presence controls. Those controls add highs and lows back in the power amp section without disturbing the nice distortion tone of the gain stages. In order to implement this, however, I had to move the output of the normal channel to the ground side of R8 (removing the ground connection), to free up the second input of the PI. This leaves you with stacked tone controls, and since I'm not a fan of the normal channel single tone control, I just removed it. As Stephen pointed out in another thread, someone else posted a schematic with NFB, and "jumped" channels here:
http://www.unimind.us/images/Trinity18_ ... ematic.jpg